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With use of high-pressure and temperature, the solid/liquid interfacial tension of crude oil is reduced, which leads to the spontaneous formation of stable two-phase microdroplets. Whether such stable two-phase microdroplets can be formed is dependent on the solid/liquid interfacial tension. Microdroplets are formed in both water-in-crude oil emulsions and crude oil-in-water emulsions, even under a high pressure of 35 MPa and a temperature of 1300 °C. However, the microdroplets in the water-in-crude oil emulsion are more stable than those in the crude oil-in-water emulsion. The microdroplets were composed of an air core and a droplet shell. The droplet shell changed from gas to liquid when the temperature was increased, but the droplet volume did not change. The microdroplet size depended on the solid/liquid interfacial tension, which was different in the water-in-crude oil emulsion and the crude oil-in-water emulsion. The emulsification mechanism is considered as follows. The solid particles are driven by the liquid flow to the top of microdroplets owing to the solid/liquid interfacial tension. The top of the microdroplets moves upward, the internal pressure of the microdroplet increases, the microdroplet ruptures, and the emulsification proceeds. The simulation results are consistent with the experimental results of high-pressure and temperature-induced emulsification of crude oil.Sometimes I really need my little breaks, you know? I’ve come to accept that fact, but the experience of forgetting to take my meds comes across as a deeply alien concept, even though it’s just a small and manageable thing, the kind of forgetfulness you can work around.
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